Open AccessLead-free 0–3-type composites: From piezoelectric sensitivity to modified figures of merit
Author(s) -
А. Н. Исаева,
V. Yu. Topolov
Publication year - 2021
Publication title -
journal of advanced dielectrics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.38
H-Index - 13
eISSN - 2010-135X
pISSN - 2010-1368
DOI - 10.1142/s2010135x21500107
Subject(s) - piezoelectricity , figure of merit , anisotropy , materials science , type (biology) , composite material , ceramic , sensitivity (control systems) , monotonic function , matrix (chemical analysis) , volume fraction , physics , condensed matter physics , mathematical analysis , mathematics , optics , optoelectronics , electronic engineering , ecology , biology , engineering
Effective piezoelectric properties, electromechanical coupling factors (ECF) and figures of merit (FOM) are studied in lead-free 0–3-type composites based on novel ferroelectric 0.965([Formula: see text][Formula: see text]([Formula: see text][Formula: see text]O 3 –0.035[Formula: see text][Formula: see text][Formula: see text][Formula: see text]O 3 ceramic. Systems of prolate ceramic inclusions are surrounded by a large polymer matrix that can be either monolithic (in the 0–3 composite) or porous (in the 0–3–0 composite). Non-monotonic volume-fraction dependences of the effective piezoelectric coefficients [Formula: see text], ECF [Formula: see text], squared FOM [Formula: see text] and their modified analogs for stress-driven systems are analysed, and examples of the high longitudinal piezoelectric sensitivity ([Formula: see text][Formula: see text] 100 mV ⋅m/N) are considered. A role of microgeometrical factors, that promote the large effective parameters and anisotropy of properties in the 0–3-type composites, is highlighted. New “aspect ratio — volume fraction” diagrams are first built to describe conditions for high piezoelectric sensitivity, large modified FOM and their anisotropy in the studied composites. These advanced materials can be of value for piezoelectric sensor, energy-harvesting and related applications.