Open AccessEffect of sulfur doping on the dielectric properties of Sb2Se3 system
Author(s) -
Ragab Mahani,
E. A. ElSayad
Publication year - 2019
Publication title -
journal of advanced dielectrics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.38
H-Index - 13
eISSN - 2010-135X
pISSN - 2010-1368
DOI - 10.1142/s2010135x19500012
Subject(s) - orthorhombic crystal system , materials science , doping , dielectric , conductivity , analytical chemistry (journal) , antimony , stoichiometry , selenide , electrical resistivity and conductivity , permittivity , activation energy , phase (matter) , condensed matter physics , crystallography , chemistry , crystal structure , physics , selenium , organic chemistry , metallurgy , optoelectronics , quantum mechanics
In this paper, we report the effect of sulfur doping on the electrical and dielectric properties of semiconducting Sb 2 Se 2 S over wide ranges of temperatures (298–473[Formula: see text]K) and frequencies (42–10 6 [Formula: see text]Hz). Sb 2 Se 2 S system has been prepared by the direct fusion and cooling cycle of a mixture of the constituent elements, in stoichiometric ratio and purity 99.999%, in vacuum-sealed silica tubes. X-ray analysis showed a decrease in the cell parameters [Formula: see text], [Formula: see text] and [Formula: see text] upon doping with sulfur. However, the pure and doped Sb 2 Se 3 showed the single orthorhombic phase structure. The permittivity of Sb 2 Se 2 S showed a decrease with increasing frequency due to a decrease in the average bond strength. While, ac conductivity increased with the frequency increase, obeying the Jonscher’s universal dynamic law. The conductivity temperature dependence is well described by the correlated barrier hopping model. The activation energy calculated from DC conductivity is found at higher value (0.79[Formula: see text]eV) as compared to that reported in the literature for other antimony selenide compounds. Accordingly, a new Sb 2 Se 2 S compound is suggested which may be useful for electronic devices.