THE REACTIONS OF ACTIVE NITROGEN WITH HYDROGEN SULPHIDE AND CARBON DISULPHIDE | Zendy

R. A. Westbury | Zendy; C. A. Winkler | Zendy

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THE REACTIONS OF ACTIVE NITROGEN WITH HYDROGEN SULPHIDE AND CARBON DISULPHIDE

Author(s) -

R. A. Westbury,

C. A. Winkler

Publication year - 1960

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v60-049

Subject(s) - chemistry , nitrogen , hydrogen , dissociation (chemistry) , yield (engineering) , carbon fibers , hydrogen atom , inorganic chemistry , nitrogen atom , hydrogen sulphide , photochemistry , atmospheric temperature range , sulfur , organic chemistry , thermodynamics , group (periodic table) , physics , materials science , alkyl , composite number , composite material

The destruction of either hydrogen sulphide or carbon disulphide by active nitrogen appears to be minimal at some temperature in the range 200–250 °C. Both reactions yield large amounts of polymer.It is postulated that the main reactions involve destruction of the reactant as it acts as a third body for recombination of nitrogen atoms. As the temperature is increased, dissociation of the nitrogen atom – reactant complex apparently increases. To account for the observed temperature effects, it is assumed that reactions also occur to regenerate reactant.

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