THE REACTIONS OF ACTIVE NITROGEN WITH CHLOROMETHANES | Zendy

S. E. Sobering | Zendy; C. A. Winkler | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

THE REACTIONS OF ACTIVE NITROGEN WITH CHLOROMETHANES

Author(s) -

S. E. Sobering,

C. A. Winkler

Publication year - 1958

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v58-178

Subject(s) - chemistry , chloroform , dichloromethane , chlorine , hydrogen cyanide , cyanogen , hydrogen chloride , nitrogen , carbon tetrachloride , inorganic chemistry , chloride , hydrogen , organic chemistry , solvent

Cyanogen chloride and chlorine were the only gaseous products observed in the reaction of active nitrogen with carbon tetrachloride at 110° and 420 °C. The product yields tended towards limiting values at higher reactant flow rates, and increased with increase of temperature at all flow rates. The reactions of active nitrogen with chloroform and dichloromethane at 260° and 420 °C yielded hydrogen chloride, hydrogen cyanide, and cyanogen, in addition to cyanogen chloride and chlorine. The behavior of the product yields with reactant flow rates and temperature was similar to that of the products from carbon tetrachloride.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research