Open AccessHydrogen absorption in palladized MCM-41
Author(s) -
Colin Peter Guthrie,
Eric J. Reardon
Publication year - 2017
Publication title -
facets
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 9
ISSN - 2371-1671
DOI - 10.1139/facets-2016-0034
Subject(s) - absorption (acoustics) , hydrogen , palladium , gaseous hydrogen , analytical chemistry (journal) , materials science , chemistry , catalysis , composite material , chromatography , organic chemistry
Hydrogen absorption by palladium (Pd) in Pd/MCM-41 was studied at 298.2 ± 0.1 K and between 0.5 and 1.0 atm [Formula: see text]. Mass percent Pd loadings of 0.81%, 1.10%, 1.16%, and 2.30% of total Pd/MCM-41 were used. Absorption was measured in gas-tight stainless steel cells equipped with computer-logged pressure transducers. The average maximum hydrogen absorption for all samples was 0.85 ± 0.18 H/Pd. An apparent trend of increasing hydrogen absorption as the mass percent loading of Pd increased was determined to be non-significant. Similar experiments using Pd black showed a lower absorption of 0.79 ± 0.09 H/Pd.