Open AccessThe Acid - Catalysed Hydrolysis Of Sulphinate Esters
Author(s) -
Azhari Salleh
Publication year - 1983
Publication title -
jurnal teknologi/jurnal teknologi
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.191
H-Index - 22
eISSN - 2180-3722
pISSN - 0127-9696
DOI - 10.11113/jt.v3.678
Subject(s) - hydrolysis , chemistry , aqueous solution , entropy (arrow of time) , kinetic energy , thermodynamics , physics , organic chemistry , quantum mechanics
Hidrolisis berbagai ester sulfinat dalam larutan berair asid galian telah dikaji secara kinetik. Analisis data kinetik yang diperolehi mengikut kaedah Dunnett dan Bunnett-Olsen dan entropi keaktifan menunjukkan bahawa hidrolisis berlaku mengikut mekanisma A-2. The hydrolysis of substituted sulphinate esters in aqueous mineral acids have been kinetically studied. Analysis of the kinetic data by Dunnett and Bunnett-Olsen criteria and by entropy of activation suggest that the hydrolysis proceed with an A-2 mechanism.