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Degradation of phenol using mill scale as a Fenton‐type catalyst
Author(s) -
SalazarArias Ángela M.,
GiraldoGómez Gloria I.,
SanabriaGonzález Nancy R.
Publication year - 2020
Publication title -
water and environment journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 37
eISSN - 1747-6593
pISSN - 1747-6585
DOI - 10.1111/wej.12516
Subject(s) - phenol , mill scale , catalysis , paper mill , mineralization (soil science) , chemistry , degradation (telecommunications) , pulp and paper industry , waste management , nuclear chemistry , materials science , metallurgy , organic chemistry , computer science , nitrogen , telecommunications , effluent , engineering
The oxidation of phenol using mill scale (waste material produced during the hot rolling of steel) as iron source in a type Fenton process was investigated in this work. The mill scale was characterized by XRF, FT‐IR, XRD and SEM. The oxidation tests were carried at 25°C and atmospheric pressure, controlling the pH to 3.7. The phenol conversion and total organic carbon (TOC) removal as a function of catalyst loading (300–1000 mg/L) and phenol concentration (47 and 100 mg/L) were evaluated. The mill scale achieved high conversion of phenol (between 60.8 ± 2.2 and 94.5 ± 2.5%) and mineralization to CO 2 (between 38.9 ± 1.2 and 55.6 ± 2.5%) after 4‐h reaction. The mill scale showed a good catalytic performance, even after three cycles of reaction. Therefore, utilizing mill scale as a catalyst of the Fenton process is an alternative to the use of waste in the steel industry.