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A new approach to geobarometry by combining fluid inclusion and clumped isotope thermometry in hydrothermal carbonates
Author(s) -
Honlet Robin,
Gasparrini Marta,
Muchez Philippe,
Swennen Rudy,
John Cédric M.
Publication year - 2018
Publication title -
terra nova
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.353
H-Index - 89
eISSN - 1365-3121
pISSN - 0954-4879
DOI - 10.1111/ter.12326
Subject(s) - dolomite , geology , carbonate , hydrothermal circulation , mineralogy , diagenesis , geochemistry , fluid inclusions , quartz , breccia , carbonate minerals , calcite , inclusion (mineral) , paleontology , chemistry , organic chemistry
This study presents a new approach to geobarometry by combining fluid inclusion and clumped isotope (Δ 47 ) thermometry on carbonate minerals. The offset between homogenisation temperatures of primary fluid inclusions with known composition and Δ 47 temperatures of the host mineral allows a direct estimation of the fluid pressure at the time of carbonate crystallisation. This new approach is illustrated via hydrothermal dolomite samples from the Variscan foreland fold‐and‐thrust belt in northern Spain. Clumped isotope analyses yield crystallisation temperatures (107–168°C) which are higher than homogenisation temperatures in corresponding samples (95–145°C). The calculated pressure values suggest that dolomitizing fluids were overpressured during formation of zebra dolomite textures, whereas lower pressures are obtained for dolomite cement from breccia textures. This new approach to geobarometry opens up the possibility of estimating the pressure of carbonate crystallisation and has potential applications in diagenesis, basin analysis, ore geology and tectonics.