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The Effect of pH Values on the Synthesis, Microstructure and Photocatalytic Activity of Ce‐Bi 2 O 3 by a Two‐Step Hydrothermal Method
Author(s) -
Zhang Fengjun,
Lu Wei,
Xiao Guosheng,
Liu Zhuojing,
Xing Fanwei,
Lyu Cong
Publication year - 2015
Publication title -
photochemistry and photobiology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.818
H-Index - 131
eISSN - 1751-1097
pISSN - 0031-8655
DOI - 10.1111/php.12496
Subject(s) - photocatalysis , band gap , microstructure , tetragonal crystal system , materials science , methyl orange , visible spectrum , hydrothermal circulation , irradiation , oxide , nuclear chemistry , crystal structure , mineralogy , analytical chemistry (journal) , chemistry , catalysis , chemical engineering , crystallography , composite material , metallurgy , chromatography , physics , optoelectronics , nuclear physics , engineering , biochemistry
In this study, the effect of pH values on the microstructure and photocatalytic activity of Ce‐Bi 2 O 3 under visible light irradiation was investigated in detail. In alkaline condition ( e.g . pH = 9), the as‐prepared Ce‐Bi 2 O 3 exhibited an agglomerated status and mesoporous structures without a long‐range order. While in weak acid condition ( e.g . pH = 5), the Ce‐Bi 2 O 3 exhibited a best morphology with irregular nanosheets. Correspondingly, it possessed largest surface area (24.641 m 2 g −1 ) and pore volume (9.825E‐02 cm 3 g −1 ). These unique nanosheets can offer an attachment for pollutant molecules and reduce the distance of electron immigration from inner to surface, thus facilitating the separation of photoelectron and hole pairs. Compared with the pure Bi 2 O 3 , the band gap of Ce‐Bi 2 O 3 prepared at different pH was much lower. Among them, the band gap of Ce‐Bi 2 O 3 ( pH of 5) was lowest (2.61 eV ). Ce‐Bi 2 O 3 ( pH of 5) exhibited as tetragonal crystal with the bismuth oxide in the form of the composites, which could reduce the band gap width or suppress the charge‐carrier recombination, subsequently possessing great photocatalytic activity for acid orange II under visible light irradiation. After 2 h degradation under visible light, the degradation rate of acid Orange II was up to 96.44% by Ce‐Bi 2 O 3 prepared at pH 5. Overall, it can be concluded that the pH values had effects on the microstructure and photocatalytic activity of Ce‐Bi 2 O 3 catalysts.