Premium
Photocatalytic Activity of LaSr 2 AlO 5 :Eu Ceramic Powders
Author(s) -
García Carlos R.,
Oliva Jorge,
DíazTorres Luis A.
Publication year - 2015
Publication title -
photochemistry and photobiology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.818
H-Index - 131
eISSN - 1751-1097
pISSN - 0031-8655
DOI - 10.1111/php.12428
Subject(s) - photoluminescence , scanning electron microscope , analytical chemistry (journal) , materials science , photocatalysis , methylene blue , europium , tetragonal crystal system , absorbance , annealing (glass) , ceramic , nuclear chemistry , mineralogy , luminescence , chemistry , crystallography , crystal structure , metallurgy , optoelectronics , composite material , environmental chemistry , biochemistry , chromatography , catalysis
The photocatalytic activity, of undoped and Europium‐doped LaSr 2 AlO 5 powders, has been investigated by degrading methylene blue dye in water solutions. Those powders were fabricated by a combustion method and an annealing treatment in air. All samples showed a tetragonal single phase according to by X‐ray diffraction measurements ( XRD ). Scanning electron microscopy ( SEM ) revealed irregular semi‐oval grains with sizes in the range of 3.5–4.27 μ m. Photoluminescence spectrum showed sharp emission peaks at 588 nm and at 617 nm which are associated with 7 F 1 , 7 F 2 → 5 D 0 Eu 3+ ion forbidden transitions, respectively, under UV light excitation of 322 nm. The methylene blue ( MB ) degradation under UV light (254 nm) was studied by monitoring changes in the absorbance peak of MB at 665 nm. Finally, LaSr 2 AlO 5 :Eu powders were used three times and the efficiency for the degradation of MB decreased from 100 to 61% after the third cycle of use.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom