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Early solar system aqueous activity: K isotope evidence from Allende
Author(s) -
Jiang Yun,
Koefoed Piers,
Pravdivtseva Olga,
Chen Heng,
Li ChunHui,
Huang Fang,
Qin LiPing,
Liu Jia,
Wang Kun
Publication year - 2021
Publication title -
meteoritics and planetary science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.09
H-Index - 100
eISSN - 1945-5100
pISSN - 1086-9379
DOI - 10.1111/maps.13588
Subject(s) - allende meteorite , chondrule , formation and evolution of the solar system , chondrite , carbonaceous chondrite , parent body , isotope , chemistry , alkali metal , analytical chemistry (journal) , trace element , mineralogy , meteorite , geology , geochemistry , astrobiology , environmental chemistry , physics , organic chemistry , quantum mechanics
The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K 2 O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ 41 K: −0.30 to −0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K 2 O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ 41 K: −0.87‰ to −0.24‰). The matrix and bulks are nearly identical in K 2 O content and K isotope compositions (0.02–0.05 wt%; δ 41 K: −0.62 to − 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.