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Effect of annealing on the magnetic states of FEBID‐grown cobalt nanopatterns examined by off‐axis electron holography
Author(s) -
ALMEIDA T.,
MCGROUTHER D.,
KOVÁCS A.,
DUNINBORKOWSKI R.,
MCVITIE S.
Publication year - 2020
Publication title -
journal of microscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.569
H-Index - 111
eISSN - 1365-2818
pISSN - 0022-2720
DOI - 10.1111/jmi.12869
Subject(s) - electron holography , transmission electron microscopy , annealing (glass) , cobalt , electron beam induced deposition , nanotechnology , materials science , electron microscope , crystallite , nanostructure , chemical engineering , chemistry , analytical chemistry (journal) , crystallography , scanning transmission electron microscopy , composite material , optics , metallurgy , physics , engineering , chromatography
Summary The growth of cobalt nanopatterns (NPs) using focused electron‐beam induced deposition (FEBID) for localised magnetic studies is presented. The initial FEBID products are shown to be polycrystalline and form hetero‐structured core‐shell NPs through surface oxidation. Off‐axis electron holography is performed to reconstruct their morphology, thickness profile and image their individual magnetic vortex domain states. In situ annealing to 400°C promoted migration of the Co‐overspray to grow the Co NPs and improved their crystallinity through coarsening, as well as induced diffusion of embedded carbon out of their surface. It is found that the change in their morphology and chemical instability under heating restricts their suitability for examining thermally induced magnetic variations. Lay Description In this paper, electron microscopy is used to deposit magnetic cobalt nanopatterns and characterise the effect of in‐situ heating on their chemistry, structure and magnetic properties. The electron beam of the secondary electron microscope is used to dissociate an injected precursor gas near the SiN membrane substrate of in‐situ transmission electron microscopy (TEM) chips and locally deposit the elemental Co in circular patterns ∼ 90 nm in diameter. TEM reveals formation of a Co‐oxide shell and embedding of carbon from the precursor gas during growth. The technique of electron holography is used to image the magnetism of the core‐shell Co / Co‐oxide nanopatterns, which are shown to exhibit magnetic vortex states. In‐situ annealing results in migration of the Co overspray to increase their height and carbon diffusion from their surface, as well as change in their original magnetic state through change of orientation. It is found that the change in the morphology and chemistry of Co nanopatterns under heating limits their use for studying the effect of temperature on their magnetism in isolation.