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Experimental determination of REE partition coefficients between zircon, garnet and melt: a key to understanding high‐ T crustal processes
Author(s) -
Taylor R. J. M.,
Harley S. L.,
Hinton R. W.,
Elphick S.,
Clark C.,
Kelly N. M.
Publication year - 2015
Publication title -
journal of metamorphic geology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.639
H-Index - 114
eISSN - 1525-1314
pISSN - 0263-4929
DOI - 10.1111/jmg.12118
Subject(s) - zircon , geology , metamorphism , geochemistry , granulite , anatexis , crust , silicate , partition coefficient , pelite , partial melting , mineralogy , petrology , geomorphology , chemistry , chromatography , facies , structural basin , organic chemistry
The partitioning of rare earth elements ( REE ) between zircon, garnet and silicate melt was determined using synthetic compositions designed to represent partial melts formed in the lower crust during anatexis. The experiments, performed using internally heated gas pressure vessels at 7 kbar and 900–1000 °C, represent equilibrium partitioning of the middle to heavy REE between zircon and garnet during high‐grade metamorphism in the mid to lower crust. The D REE (zircon/garnet) values show a clear partitioning signature close to unity from Gd to Lu. Because the light REE have low concentrations in both minerals, values are calculated from strain modelling of the middle to heavy REE experimental data; these results show that zircon is favoured over garnet by up to two orders of magnitude. The resulting general concave‐up shape to the partitioning pattern across the REE reflects the preferential incorporation of middle REE into garnet, with D G d (zircon/garnet) ranging from 0.7 to 1.1, D H o (zircon/garnet) from 0.4 to 0.7 and D Lu (zircon/garnet) from 0.6 to 1.3. There is no significant temperature dependence in the zircon–garnet REE partitioning at 7 kbar and 900–1000 °C, suggesting that these values can be applied to the interpretation of zircon–garnet equilibrium and timing relationships in the ultrahigh‐ T metamorphism of low‐Ca pelitic and aluminous granulites.