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Germanium‐antimony‐selenium‐tellurium thin films: Clusters formation by laser ablation and comparison with clusters from mixtures of elements
Author(s) -
Huang Fei,
Halenkovič Tomáš,
Baillieul Marion,
Nazabal Virginie,
Němec Petr,
Havel Josef
Publication year - 2022
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.18228
Subject(s) - antimony , tellurium , germanium , ternary operation , thin film , stoichiometry , analytical chemistry (journal) , materials science , selenium , sputter deposition , crystallography , sputtering , chemistry , metallurgy , nanotechnology , silicon , chromatography , computer science , programming language
Quaternary germanium‐antimony‐selenium‐tellurium (Ge‐Sb‐Se‐Te) thin films deposited from Ge 19.4 Sb 16.7 Se 63.9− x Te x ( x = 5, 10, 15, and 20) glass‐ceramics targets by radio frequency magnetron sputtering were studied using laser ablation quadrupole ion trap time of flight mass spectrometry. Binary, ternary, and quaternary Ge a Sb b Se c Te d clusters were formed and their stoichiometry was determined. By comparison of the clusters obtained from quaternary Ge‐Sb‐Se‐Te thin films and those from ternary Ge‐Sb‐Te materials, we found that Ge‐Te species are not detected from the quaternary system. Furthermore, Ge‐Se and Se‐Te species are missing in mass spectra generated from Ge‐Sb‐Se‐Te thin films. From the Ge‐Sb‐Se‐Te thin films, 16 clusters were detected while ternary Ge‐Sb‐Se glasses yielded 26 species. This might be considered as a signal of higher stability of Ge‐Sb‐Se‐Te thin films which is increasing with a higher content of Te. The missing (Se 2 + , Ge a Sb + ( a = 1–4), and GeSe c + ( c = 1, 2)) and new (Ge + and Sb b Te + ( b = 1–3)) clusters may indicate that some of the structural features of the films (Ge 2 Se 6/2 and Se 2 Sb‐SbSe 2 ) were replaced by (GeSe 4− x Te x and SbSe 3− x Te x ) ones. In addition, when comparing the stoichiometry of clusters formed from Ge‐Sb‐Se‐Te thin films with those from the mixtures of the elements, only Sb 3 + and SbSe + were observed in both cases. The knowledge gained concerning clusters stoichiometry contributes to the elucidation of the processes proceeding during plasma formation used for the chalcogenide thin films deposition.