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Nonlinear dielectric response and positive dielectric tunability in antipolar CaTiSiO 5
Author(s) -
Murata Tomoki,
Asaka Toru,
Hirose Sakyo
Publication year - 2021
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.17968
Subject(s) - dielectric , materials science , antiferroelectricity , electric field , ferroelectricity , permittivity , condensed matter physics , titanite , dielectric loss , optoelectronics , composite material , physics , quartz , quantum mechanics
Dielectric tunability has been extensively investigated in ferroelectric materials, which exhibit a negative tunability of dielectric permittivity in an external electric field. In contrast, positive tunability is rare and has been reported only in a few antiferroelectric materials. We present positive (and negative) tunability in the titanite, CaTiSiO 5 . The dielectric property of CaTiSiO 5 was measured up to an extraordinarily high electric field of 40 MV/m. A nonlinear polarization field loop with no hysteresis was obtained. The dielectric permittivity of ε r ~ 25 increases up to ε r ~ 40 at 20 MV/m and room temperature. Although titanite has an antipolar structure and is expected to be “antiferroelectric,” its dielectric response in high electric fields up to ~40 MV/m differs from that of conventional antiferroelectrics. We demonstrate that the phase‐transition temperature and dielectric tunability could be modulated through the chemical substitution of Ca 1− x La x TiSi 1− x Al x O 5 , in which the destabilization of the long‐range antipolar order is revealed by transmission electron microscopy analysis. These results indicate that the observed dielectric response to an electric field may originate from the unique features of the antipolar and domain structures in CaTiSiO 5 .