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Y 3 NbO 7 transparent ceramic series for high refractive index optical lenses
Author(s) -
Huang Muzhang,
Li Lieyang,
Feng Yingjie,
Zhao Xiaohui,
Pan Wei,
Wan Chunlei
Publication year - 2021
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.17953
Subject(s) - refractive index , materials science , transparent ceramics , transmittance , ceramic , natural bond orbital , sintering , optics , analytical chemistry (journal) , mineralogy , composite material , optoelectronics , chemistry , density functional theory , computational chemistry , physics , chromatography
A 2 B 2 O 7 and A 3 BO 7 transparent ceramic families are potential materials for optical lenses because of their high refractive index. Although nonstoichiometry is widely present in these material families, its effect on refractive index and optical properties has not yet been fully studied. In this study, optical properties are reported for the Y 3 NbO 7 transparent ceramic series, Y 1− x Nb x O 1.5+ x ( x = 0.20, 0.22, 0.24, 0.25, 0.26), which were fabricated by a pressureless pre‐sintering and a hot isostatic pressing post‐sintering treatment. The refractive index increases from 2.04 to 2.10 (at 587.6 nm) as the Nb content x increases, which is mainly attributed to the variation in the oxygen ion/vacancy ratio. The Abbe number is larger than 40, showing a decreasing trend as the Nb content x increases. The specimen with x = 0.24 has the highest inline transmittance, which were 62% and 76% at 587.6 and 2000 nm, respectively, for a 1‐mm‐thick specimen. Through the approach of nonstoichiometry, Y 1− x Nb x O 1.5+ x series exhibit balanced properties of refractive index, Abbe number, and transmittance, which can be considered as a promising candidate for high refractive index optical lenses.