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Deep‐red‐emitting SrLaLiTeO 6 : Mn 4+ double perovskites: Correlation between Mn 4+ ‐O 2− bonding and photoluminescence
Author(s) -
Lal Sariga C.,
Naseemabeevi Jawahar I.,
Ganesanpotti Subodh
Publication year - 2021
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.17910
Subject(s) - phosphor , photoluminescence , ion , isostructural , quantum yield , raman spectroscopy , analytical chemistry (journal) , crystal structure , thermal stability , monoclinic crystal system , materials science , chemistry , crystallography , optoelectronics , physics , fluorescence , optics , organic chemistry , chromatography
Mn 4+ ‐activated deep red‐emitting SrLaLiTeO 6 phosphors are investigated for indoor plant growth LED applications for the first time. The phosphors crystallize in monoclinic ( P 2 1 / n ) symmetry is isostructural with SrLaLiTeO 6 host. B‐site substitution of Mn 4+ ions is confirmed from the redshift of high energy phonon modes in both Raman and IR spectra. The phosphor exhibited a far‐red emission centered at 696 nm corresponding to the 2 E g → 4 A 2g spin‐forbidden transition of the Mn 4+ ions. Approximate crystal field parameters depict the weak influence of neighboring ligand fields on Mn 4+ ions and the least covalence of Mn 4+ ‐ligand bonding compared to other double perovskite phosphors. Moreover, the phosphors exhibit excellent thermal stability with an activation energy of 0.23 eV. Phosphor parameters including CCT, color purity, and quantum yield are evaluated and their values meet the requirements of a red‐emitting phosphor for LED applications. Furthermore, the PL emission spectrum of SrLaLiTeO 6 : Mn 4+ matches with the absorption spectrum of plant phytochromes denoting the prospects of this phosphor for indoor plant growth LED applications.