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Enhanced luminescence and thermal stability of (Sr,Ca)AlSiN 3 :Eu 2+ via superficial organic carbon modification
Author(s) -
Tian Junhang,
Zhuang Weidong,
Liu Ronghui,
Liu Yuanhong,
Chen Guantong,
Chen Siwei,
Jiang Ze
Publication year - 2021
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.17809
Subject(s) - phosphor , luminescence , thermal stability , materials science , carbon fibers , nitride , quenching (fluorescence) , impurity , surface modification , chemistry , chemical engineering , nanotechnology , composite material , optoelectronics , organic chemistry , fluorescence , optics , physics , layer (electronics) , engineering , composite number
Abstract The Eu 2+ ‐activated nitride phosphors have been widely used in solid‐state lighting, but the applications in high‐power white‐light‐emitting diodes (wLEDs) field require higher thermal stability of luminescent materials. The oxidation of Eu 2+ and the damage of nitride host in the Eu 2+ ‐activated nitride phosphors are the two crucial reasons for the luminescence loss while operating. A superficial organic carbon modification is performed on the red‐emitting (Sr,Ca)AlSiN 3 :Eu 2+ phosphor via the incorporation of organic carbon by solution mixing and thermal post‐treatment under the N 2 ‐H 2 atmosphere. After the superficial organic carbon modification, the oxidation of Eu 2+ and the formation of impurity phases on the phosphor surface are effectively reduced. When the superficial organic carbon modified sample was treated in the 2 wt.% sucrose solutions, the relative brightness is strengthened by 2.15%, the thermal quenching characteristic is improved by 8.9% at 300℃, and the aging test results show an excellent thermal stability. All above indicate that the superficial organic carbon modification is a promising technique to enhance the thermal stability of analogous Eu 2+ ‐activated nirtide phosphors.