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Effect of the pyrolysis atmosphere on the mechanical properties of polymer‐derived SiOC and SiCN
Author(s) -
Sorarù Gian Domenico,
Tavonatti Consuelo,
Kundanati Lakshminath,
Pugno Nicola,
Biesuz Mattia
Publication year - 2020
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.17392
Subject(s) - nanoindentation , materials science , pyrolysis , composite material , elastic modulus , indentation hardness , vickers hardness test , inert gas , hardness , polymer , chemical engineering , microstructure , engineering
Abstract Mechanical properties of polymer‐derived ceramics are usually measured on samples pyrolyzed in inert atmosphere. Here, we report the hardness and elastic modulus of SiOC and SiCN pyrolyzed in both inert (Ar) and reactive (CO 2 ) atmosphere. The external surface of the specimens exposed to the pyrolysis gas was characterized by Vickers microhardness measurements and infrared spectroscopy. The elastic modulus was evaluated by three‐point bending tests on thin (150‐200 µm) and dense specimens. Polished sections of the SiOC samples were prepared to study, by energy‐dispersive X‐ray spectroscopy (EDXS) and nanoindentation, how the elemental composition, hardness, and elastic modulus vary from the surface toward the bulk. For both compositions, pyrolysis in CO 2 leads to a strong decrease in the hardness and elastic modulus. The hardness of both the samples pyrolyzed in CO 2 approaches the typical value for fused silica, suggesting that CO 2 selectively breaks the Si–C and Si–N bonds and leads to the formation of a silica‐like network. EDXS and nanoindentation reveal that the modification induced by the CO 2 flow extends below the surface at least for a thickness of about 30 µm.