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Critical role of cationic local stresses on the stabilization of entropy‐stabilized transition metal oxides
Author(s) -
Bhaskar Lalith K.,
Nallathambi Varatharaja,
Kumar Ravi
Publication year - 2020
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.17029
Subject(s) - materials science , ion , phase transition , crystallite , cationic polymerization , chemical physics , metal , lattice (music) , metal ions in aqueous solution , thermodynamics , chemistry , metallurgy , polymer chemistry , physics , organic chemistry , acoustics
Entropy‐stabilized transition metal oxides ([MgNiCoCuZn]O) (ESO) in recent years have received considerable attention owing to their unique functional properties. Solution combustion and solid state syntheses resulted in crystallites varying from 5‐15 nm to 3‐5 μm respectively. Phase stability studies showed that all the systems containing Cu 2+ ions in the ESO lattice segregated upon slow cooling in the furnace. It was only when ESO was quenched in air from 1000°C the lattice stabilized to a single phase. Experiments concomitant with molecular dynamics (MD) simulations demonstrated that the local stress fields around the cations played a critical role in stabilizing the single phase. The local stress fields are a result of Jahn‐Teller distortion induced by the Cu 2+ ions in the lattice. It is clearly established that in the absence of the minimization of the local stress fields around the Cu 2+ ions, segregation leading to the formation of a multi‐phase material is imminent for this particular composition.