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Influence of grain interior and grain boundaries on transport properties of scandium‐doped calcium zirconate
Author(s) -
Ding Yushi,
Li Ying,
Huang Wenlong
Publication year - 2020
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.16968
Subject(s) - partial pressure , grain boundary , oxygen transport , scandium , oxygen , perovskite (structure) , conductivity , hydrogen , electrolyte , materials science , thermal conduction , grain size , analytical chemistry (journal) , inorganic chemistry , chemistry , electrode , microstructure , crystallography , metallurgy , composite material , organic chemistry , chromatography
Calcium zirconate‐based protonic conductors are currently the most promising electrolyte for high‐temperature hydrogen sensors, however, protonic conductors exhibit mixed protons, oxygen vacancies and electron‐holes conduction above 700°C, and the protons transport number is significantly influenced by the atmosphere. Therefore, the relationship between protons transport number and oxygen/water vapor partial pressure should be established to improve the veracity of the hydrogen sensor. Herein, CaZr 0.9 Sc 0.1 O 3‐ α perovskite oxides are prepared and the influence of grain interior and grain boundaries on transport properties is systematically investigated by using with defect chemistry theory. And the relationship between protons transport number and oxygen/water vapor partial pressure should be obtained. The results indicate that the dominant conduction carriers of CaZr 0.9 Sc 0.1 O 3‐ α were protons in Ar and reductive atmospheres at 500°C‐800°C, and the conductivity ( σ h · ) and transport number ( t h · ) of holes are remarkably increased with increasing oxygen partial pressure. In addition, protons, oxygen vacancies and electron‐holes transport properties of grain interior and grain boundaries in scandium‐doped calcium zirconate reveal that grains can effectively block oxygen vacancies transport at 550°C‐800°C, but grains cannot block the holes transport. Therefore, the oxygen vacancies trend to transport through grain boundaries.