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Synthesis and structure determination of calcium silicate‐cellulose nanograss biocomposite
Author(s) -
Biswas Nilormi,
Samanta Aniruddha,
Mitra Sanchali,
Biswas Ripan,
Podder Soumik,
Sanyal Ambarish,
Ghosh Jiten,
Ghosh Chandan Kumar,
Mukhopadhyay Anoop Kumar
Publication year - 2020
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.16957
Subject(s) - calcium silicate , silicate , materials science , cellulose , biocomposite , wollastonite , chemical engineering , calcium , composite material , phase (matter) , mineralogy , chemistry , composite number , organic chemistry , raw material , engineering , metallurgy
The 100% phase pure calcium silicate nanoparticles (CSNPs) of the α‐wollastonite phase by hydrothermal synthesis is achieved first. Next this work reports the first‐ever microwave‐assisted low temperature synthesis of calcium silicate‐cellulose nanograss composites. The characterization by FESEM studies confirm that calcium silicate‐cellulose composites possess the nanograss like morphology spread over the matrix of calcium silicate. The structural information of the calcium silicate‐cellulose composites are derived by both theoretical and experimental techniques. Low‐energy ground state geometrical structures of the cellulose on the triclinic wollastonite surfaces and their interactions have been primarily determined by Density Functional Theory. Accordingly, the short‐range structural information is confirmed by Pair Distribution Function analysis. Structural information along with binding interactions are also confirmed from X‐ray photoelectron spectroscopy. The implications of these detailed analysis of structures in tuning the properties of such ceramic polymeric hybrid composites for futuristic endodontic application is discussed.