Re‐entrant dipole glass‐like behavior and lattice dynamics of 0.65Bi(Mg 1/2 Ti 1/2 )O 3 ‐0.35PbTiO 3 | Zendy

Chen Kaiyuan | Zendy; Wei Fu | Zendy; Jia Liu | Zendy; Tianxiang Yan | Zendy; Lan Zhencheng | Zendy; Fang Liang | Zendy; Peng Biaolin | Zendy; Wang Dawei | Zendy; Liu Laijun | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Re‐entrant dipole glass‐like behavior and lattice dynamics of 0.65Bi(Mg 1/2 Ti 1/2 )O 3 ‐0.35PbTiO 3

Author(s) -

Chen Kaiyuan,

Wei Fu,

Jia Liu,

Tianxiang Yan,

Lan Zhencheng,

Fang Liang,

Peng Biaolin,

Wang Dawei,

Liu Laijun

Publication year - 2020

Publication title -

journal of the american ceramic society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.9

H-Index - 196

eISSN - 1551-2916

pISSN - 0002-7820

DOI - 10.1111/jace.16956

Subject(s) - materials science , ferroelectricity , phase boundary , raman spectroscopy , condensed matter physics , tetragonal crystal system , dielectric , permittivity , dipole , lattice (music) , ceramic , polarization (electrochemistry) , phase transition , phase (matter) , crystal structure , optics , crystallography , chemistry , physics , composite material , optoelectronics , organic chemistry , acoustics

The 0.65Bi(Mg 1/2 Ti 1/2 )O 3 ‐0.35PbTiO 3 (0.65BMT‐0.35PT) ceramic, nearby morphotropic phase boundary (MPB), between tetragonal and rhombohedral was prepared. Dielectric permittivity dependence of temperature exhibits a re‐entrance dipole glass‐like behavior near room temperature. The behavior was described by the Vogel‐Fulcher law and the new glass model . Furthermore, a phenomenological statistical model was employed to determine the distribution of clusters dependence of temperature. The lattice dynamics of the 0.65BMT‐0.35PT ceramic was estimated by Raman spectroscopy from 298‐723 K. A disruption of ferroelectric long‐range order and an occurrence of local lattice distortion were revealed. The relaxor‐ferroelectric (r‐FE) nature of the 0.65BMT‐0.35PT was characterized by polarization‐electric field P(E) . A close relation between the distribution of clusters and ferroelectric properties was established.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research