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Insights into the direct formation of [Ca 24 Al 28 O 64 ] 4+ (4e − ) and its electrical characterization
Author(s) -
Li Fan,
Zhang Xin,
Liu Hongliang
Publication year - 2020
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.16769
Subject(s) - homogeneous , electron , materials science , lattice (music) , characterization (materials science) , chemical physics , nanotechnology , chemical engineering , crystallography , chemistry , physics , thermodynamics , quantum mechanics , acoustics , engineering
C12A7:e − electrides are potentially useful in various technological applications. However, it usually needs to be synthesized through a complicated multistep process under severe conditions. Therefore, the search is on for a more facile and direct process that occurs under milder conditions. Here, a facile and efficient synthesis strategy has been developed for the rapid production of highly conductive C12A7:e − directly from commercially available chemical ingredients of CaO, Al 2 O 3 , and Al powders at 1200°C in a 10 −2 Pa vacuum for 20 minutes using SPS process. The electron concentration in the as‐prepared C12A7:e − was enhanced up to 2.13 × 10 21 cm −3 by simply regulating the addition amounts of Al, covering IM transition. The electronic structure results indicated the formation of homogeneous trapped electrons in the lattice. Further thermal analyses illustrated that Al made a dual function of reducing agent and and reaction promoter, which remarkably reduced the formation temperature of mayenite structure. This study fills in the gaps of direct formation mechanisms of conductive mayenite phase, and provides a new perspective to regulate the resultant N e .