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Near‐ultraviolet light–induced dazzling red emission in CaGd 2 (MoO 4 ) 4 :2 x Sm 3+ compounds for phosphor‐converted WLEDs
Author(s) -
Zhou Luhui,
Du Peng,
Yu Jae Su
Publication year - 2019
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.16419
Subject(s) - phosphor , color temperature , luminescence , emission spectrum , quantum efficiency , color rendering index , ultraviolet , light emitting diode , engraving , analytical chemistry (journal) , chemistry , materials science , optoelectronics , spectral line , physics , organic chemistry , composite material , astronomy
The Sm 3+ ‐activated CaGd 2 (MoO 4 ) 4 phosphors were prepared through a sol‐gel reaction route. From the results of excitation spectrum, three‐dimensional emission spectra and contour lines, it was confirmed that the near‐ultraviolet (NUV) light was the proper excitation light source for the synthesized phosphors. Under 405 nm irradiation, the luminescent behaviors of the studied samples were revealed to be dependent on the Sm 3+ ion concentration and its optimal value of 0.03 mol was obtained. Through theoretical analysis, it is evident that the dipole‐dipole interaction can be responsible for the involved concentration quenching mechanism in the final products and the critical distance was 39.7 Å. Moreover, the temperature‐dependent emission spectra demonstrated that the studied samples had admirable thermal stability and the activation energy was decided to be 0.21 eV. Furthermore, the internal quantum efficiency of the Sm 3+ ‐activated CaGd 2 (MoO 4 ) 4 phosphors was found to be 21.6%. Finally, to explore the practical applications of obtained compounds for indoor illumination, a white light‐emitting diode (WLED) device which contained a NUV chip, prepared phosphors, and commercial blue‐emitting and green‐emitting phosphors was packaged. The packaged WLEDs device can emit dazzling white light with satisfied color coordinate of (0.305, 0.318), proper color rendering index (82.6), and correlated color temperature (7069 K).