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Enhanced spontaneous polarization in double perovskite Bi 2 FeCrO 6 films
Author(s) -
Meng Dehuan,
Xiao Yunsheng,
He Hongcai,
Liao Yulong,
Zhang Huaiwu,
Zhai Junyi,
Chen Zuhuang,
Martin Lane W.,
Bai Feiming
Publication year - 2019
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.16386
Subject(s) - superlattice , pulsed laser deposition , materials science , epitaxy , ferroelectricity , thin film , diffraction , polarization (electrochemistry) , perovskite (structure) , condensed matter physics , analytical chemistry (journal) , crystallography , optics , dielectric , chemistry , optoelectronics , nanotechnology , physics , layer (electronics) , chromatography
We report the pulsed‐laser deposition of epitaxial double‐perovskite Bi 2 FeCrO 6 (BFCO) films on the (001)‐, (110), and (111)‐oriented single‐crystal SrTiO 3 substrates. All of the BFCO films with various orientations show the1 / 2 1 / 2 1 / 2and3 / 2 3 / 2 3 / 2superlattice‐diffraction peaks. The intensity ratios between the1 / 2 1 / 2 1 / 2 ‐superlattice and the main 111‐diffraction peak can be tailored by simply adjusting the laser repetition rate and substrate temperature, reaching up to 4.4%. However, both optical absorption spectra and magnetic measurements evidence that the strong superlattice peaks are not correlated with the B ‐site Fe 3+ /Cr 3+ cation ordering. Instead, the epitaxial (111)‐oriented Bi 2 FeCrO 6 films show an enhanced remanent polarization of 92 μC/cm 2 at 10 K, much larger than the predicted values by density‐functional theory calculations. Positive‐up‐negative‐down (PUND) measurements with a time interval of 10 μs further support these observations. Therefore, our experimental results reveal that the strong superlattice peaks may come from A ‐ or B ‐site cation shifts along the pseudo‐cubic [111] direction, which further enhance the ferroelectric polarization of the BFCO thin films.