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ZnO‐activated formation of phase pure perovskite Pb(In 1/2 Nb 1/2 )O 3 ‐Pb(Zn 1/3 Nb 2/3 )O 3 ‐PbTiO 3 powder
Author(s) -
Brova Michael J.,
Watson Beecher H.,
R. Kupp Elizabeth,
Fanton Mark A.,
Meyer Richard J.,
Messing Gary L.
Publication year - 2019
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.16296
Subject(s) - pyrochlore , perovskite (structure) , materials science , tetragonal crystal system , calcination , phase (matter) , dopant , doping , analytical chemistry (journal) , mineralogy , crystallography , crystal structure , chemistry , catalysis , biochemistry , optoelectronics , organic chemistry , chromatography
This paper reports on the phase formation of perovskite Pb(In 1/2 Nb 1/2 )O 3 ‐Pb(Zn 1/3 Nb 2/3 )O 3 ‐PbTiO 3 ( PIN ‐ PZN ‐ PT ) powder when doped with 0.04 to 0.83 mol% ZnO. Air calcination of undoped powder mixtures for 4 hours at 800°C resulted in a mixture of Pb 2 Zn 0.29 Nb 1.71 O 6.565 pyrochlore, PIN ‐ PZN ‐ PT perovskite, and In 2 O 3 . ZnO dopant concentrations as low as 0.04 mol% increased the rate of perovskite formation and resulted in near phase pure perovskite powder of 0.5 μm particle size when heated at 800°C in air. In all cases PbTiO 3 and Pb(In 1/2 Nb 1/2 )O 3 formed prior to PIN ‐ PZN ‐ PT formation. ZnO doping promotes perovskite phase formation by increasing the reactivity of the intermediate pyrochlore phase by substituting Zn 2+ on Nb 5+ sites and forming oxygen vacancies when heated in air. Heating in high P O 2resulted in an incomplete reaction and a mixture of perovskite and pyrochlore whereas low P O 2resulted in phase separation into a mixture of rhombohedral perovskite, tetragonal perovskite, and pyrochlore. The P O 2sensitivity clearly shows that oxygen vacancies due to ZnO‐doping are critical for synthesis of phase pure PIN ‐ PZN ‐ PT powder.