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Simultaneous realization of high transparency and piezoelectricity in low symmetry KNN ‐based ceramics
Author(s) -
Zhao Xumei,
Chao Xiaolian,
Wu Di,
Liang Pengfei,
Yang Zupei
Publication year - 2019
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.16189
Subject(s) - piezoelectricity , transmittance , ceramic , materials science , transparency (behavior) , grain size , optical transparency , transparent ceramics , orthorhombic crystal system , composite material , phase transition , phase (matter) , optoelectronics , crystal structure , crystallography , condensed matter physics , computer science , chemistry , physics , computer security , organic chemistry
Transparent piezoelectric ceramic, as a lead‐free multifunctional ceramic, is in dire need of development for future high‐tech industries. However, excellent piezoelectricity and high transmittance are usually hard to achieve simultaneously, mainly due to the two mutual restricting factors (phase structure and grain size). In this work, we report that high piezoelectricity and transmittance can be obtained simultaneously in K 0.5 Na 0.5 NbO 3 ceramics via Sr(Sc 0.5 Nb 0.5 )O 3 ( SSN ) modification. The superior piezoelectric performance comes from the retain of orthorhombic phase structure at room temperature ( RT ); while the high transparency (>70% at 780 nm) can be attributed to the improved relative density and reduced grain size via SSN modification. Remarkably, in the sample with 0.05SSN modification, we realized a comprehensively high transmittance (73% at 780 nm) accompanied by a superior piezoelectric constant ( d 33 = 101 pC/N), which outperform other reported KNN ‐based transparent ceramics to our best knowledge. Our results may provide insight for further developing the transparent piezoelectric ceramics by controlling the grain size and phase structure.