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Development of a lead‐free copper co‐fired BNT ‐based piezoceramic sintered at low temperature
Author(s) -
Yesner Gregory,
Safari Ahmad
Publication year - 2018
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.15777
Subject(s) - copper , sintering , materials science , ceramic , bismuth , electrode , partial pressure , oxygen , piezoelectricity , oxide , copper oxide , metal , dielectric , lead oxide , composite material , chemical engineering , metallurgy , chemistry , optoelectronics , organic chemistry , engineering
Compatibility of Bi‐based piezoelectric ceramic and copper electrodes is demonstrated by co‐firing 0.88Bi 1/2 Na 1/2 TiO 3 –0.08Bi 1/2 K 1/2 TiO 3 –0.04BaTiO 3 ( BNKBT 88) with copper. A combination of Bi 2 O 3 , CuO, ZnO, Li 2 CO 3 , and B 2 O 3 are used as additives to reduce firing temperature to 900°C with minimal effect on the electromechanical properties compared to sintering at 1150°C without additives. Co‐firing with copper electrodes requires controlled oxygen sintering at low temperature. The atmosphere is controlled using carbon dioxide and hydrogen gas to maintain an oxygen partial pressure of 6.1 × 10 −8 atm, which is necessary for the coexistence of Cu metal and Bi 2 O 3 . The thermodynamic activity of bismuth oxide in BNKBT 88 is calculated to be 0.38. BNKBT 88 ceramics were successfully co‐fired with internal as well as surface Cu metal electrodes. The copper co‐fired ceramics were successfully polarized and the dielectric and piezoelectric properties are evaluated.