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Thermoelectric properties and stability of glasses in the Cu‐As‐Te system
Author(s) -
Vaney JeanBaptiste,
Carreaud Julie,
Morin Cédric,
Delaizir Gaëlle,
Piarristeguy Andrea,
Colas Maggy,
Cornette Julie,
Le Parc Rozenn,
Alleno Eric,
Monnier Judith,
Ribes Michel,
Escalier Raphaël,
Pradel Annie,
Pereira Gonçalves Antonio,
Branco Lopes Elsa,
Candolfi Christophe,
Lenoir Bertrand
Publication year - 2017
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.14811
Subject(s) - thermoelectric effect , materials science , spark plasma sintering , chalcogenide , raman spectroscopy , thermoelectric materials , differential scanning calorimetry , crystallization , ternary operation , thermal stability , devitrification , sintering , mineralogy , analytical chemistry (journal) , thermal conductivity , chemical engineering , metallurgy , thermodynamics , composite material , chemistry , optics , programming language , physics , chromatography , computer science , engineering
Chalcogenide glasses and more importantly their glass‐ceramics counterparts have been an interesting but very peculiar class of thermoelectric materials, with inherently low thermal conductivity (<0.3 W/m·K). In this study, we report on the fabrication of glasses in the ternary system Cu ‐ As ‐ Te ( Cu x As 55− x Te 45 [5≤ x ≤20], Cu 15 As 85− y Te y [45≤ y ≤70], and Cu 20 As 80− y Te y [45≤ y ≤65]) by melt‐quenching and subsequent spark plasma sintering treatment. Their thermal and structural properties have been studied by differential scanning calorimetry and Raman spectroscopy, leading to give insights into the structural evolution of the glassy matrix. Coupling this information with the analysis of their electrical transport properties allowed us to deepen further our understanding of the compositional effect on their thermoelectric properties, and indirectly how the evolution of their electronic band structure is at play. Despite exhibiting low ZT values by themselves, Cu ‐ As ‐ Te glasses may still be interesting candidates for thermoelectricity through partial crystallization for which knowing the relationship between composition and properties remains essential.