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Fabrication of transparent Tb 3 Al 5 O 12 ceramics by hot isostatic pressing sintering
Author(s) -
Duan Pingping,
Liu Peng,
Xu Xiaodong,
Wang Wei,
Wan Zhong,
Zhang Shouyi,
Wang Yinzhen,
Zhang Jian
Publication year - 2017
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.14810
Subject(s) - muffle furnace , hot isostatic pressing , sintering , materials science , ceramic , transparent ceramics , microstructure , differential scanning calorimetry , transmittance , metallurgy , composite material , optoelectronics , calcination , biochemistry , chemistry , thermodynamics , physics , catalysis
Tb 3 Al 5 O 12 ( TAG ) transparent ceramics were prepared by a reactive sintering method using presintering in a muffle furnace combined with hot isostatic pressing ( HIP ) sintering. The dilatometric, differential scanning calorimetry‐thermogravimetric ( DSC ‐ TG ) curves and optical quality were investigated. The microstructure evolution of the TAG ceramic samples was clarified. Two successive transformations were found to generate a TAG phase, as observed in the dilatometric and DSC ‐ TG curves and XRD patterns of TAG ceramics sintered at different temperature. The changes in average grain size and densification suggest that a 1600°C presintering temperature is suitable for HIP . The optical transmittance of the obtained 0.4 wt% TEOS : TAG transparent ceramics, which were fabricated by a new two‐step sintering of presintering at 1600°C in a muffle furnace followed by HIP at 1650°C, can reach above 80% in the visible (vis) and near‐infrared ( NIR ) regions. Its transmittance was very close to the theoretical limit. To the best of our knowledge, this is the first time that TAG transparent ceramics with ideal optical quality were obtained without vacuum sintering.