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The kinetic analysis of irreversible consecutive solid state reactions: The effect of zinc on the formation of cordierite
Author(s) -
Clark Simon M.
Publication year - 2017
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.14779
Subject(s) - cordierite , isothermal process , kinetics , zinc , solid state , kinetic energy , materials science , chemistry , thermodynamics , chemical engineering , mineralogy , catalysis , metallurgy , organic chemistry , physics , quantum mechanics , engineering
Many reactions in the solid state occur in multiple reaction steps. Here, I present a method of determining the kinetics of a two‐step consecutive reaction from isothermal, time resolved, powder diffraction data. This method is illustrated with a study of the kinetics of the formation of cordierite from a glass precursor with and without doping with zinc.