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Ethanol‐Water‐Derived Sucrose‐Coated‐Al 2 O 3 for Submicrometer AlON Powder Synthesis
Author(s) -
Xie Xiumin,
Wang Ying,
Qi Jianqi,
Wang Shanshan,
Feng Zhao,
Hou Gu,
Liu Wei,
Zhang Wei,
Xu Qiang,
Lu Tiecheng
Publication year - 2016
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.14289
Subject(s) - sucrose , materials science , particle size , carbothermic reaction , dispersity , pyrolysis , chemical engineering , ethanol , nuclear chemistry , coalescence (physics) , suspension (topology) , phase (matter) , chemistry , organic chemistry , polymer chemistry , mathematics , homotopy , pure mathematics , engineering , physics , astrobiology
Fluffy and homogenous sucrose‐coated‐γ‐Al 2 O 3 structured precursor was prepared by drying ethanol‐water sucrose/Al 2 O 3 suspension, in which the ethanol content of 85 vol% was optimized. Using the C/Al 2 O 3 mixture pyrolyzed from such precursor with 23.2 wt% sucrose, single‐phase AlON powder was synthesized by two‐step carbothermal reduction and nitridation method at 1550°C for 2 h and 1700°C for another 1.5 h. The particle size of the AlON powder was around 0.6–1.0 μm. Compared with those synthesized by the traditional approaches with mechanical C/Al 2 O 3 , Al/Al 2 O 3 , or AlN/Al 2 O 3 mixtures, the synthesis temperature was reduced about 50°C, and the AlON powder was fine and exhibited good dispersity. Such superiority of this method was attributed to that the pyrolyzed carbon film on Al 2 O 3 particle greatly restrained Al 2 O 3 coalescence during the thermal treatment.