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Fabrication and Microwave Dielectric Properties of Mg 2 SiO 4 ‐LiMgPO 4 ‐TiO 2 Composite Ceramics
Author(s) -
Cheng ZiFan,
Hu Xing,
Li Yi,
Ling ZhiYuan
Publication year - 2016
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.14276
Subject(s) - materials science , sintering , ceramic , dielectric , temperature coefficient , rutile , microwave , fabrication , composite number , analytical chemistry (journal) , mineralogy , composite material , chemical engineering , chemistry , optoelectronics , medicine , physics , alternative medicine , pathology , quantum mechanics , chromatography , engineering
Complete solid solutions between Mg 2 SiO 4 and LiMg PO 4 are confirmed by the XRD results. The phase constitution of 0.5Mg 2 SiO 4 ‐0.5LiMg PO 4 is found to be dependent on firing temperature. The chemical compatibility between Mg 2 SiO 4 and rutile phase at sintering temperature is modified by incorporating LiMg PO 4 . The microwave dielectric properties of (1− y )(0.5Mg 2 SiO 4 ‐0.5LiMg PO 4 )‐ y TiO 2 ( y = 0–0.3) composite ceramics have been investigated. The optimized microwave dielectric properties for 0.35Mg 2 SiO 4 ‐0.35LiMgPO 4 ‐0.3TiO 2 ceramics sintered at 1050°C show low dielectric constant (11.4), high‐quality factor (31 800 GHz), and low‐temperature coefficient of resonant frequency (−4 ppm/°C).