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Oxide Electrolytes for Lithium Batteries
Author(s) -
Ren Yaoyu,
Chen Kai,
Chen Rujun,
Liu Ting,
Zhang Yibo,
Nan CeWen
Publication year - 2015
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.13844
Subject(s) - electrolyte , lithium (medication) , oxide , fast ion conductor , materials science , amorphous solid , conductivity , ionic conductivity , inorganic chemistry , perovskite (structure) , chemical engineering , chemistry , metallurgy , electrode , engineering , organic chemistry , medicine , endocrinology
As the most promising candidate of the solid electrolyte materials for future lithium batteries, oxide electrolytes with high–lithium‐ion conductivity have experienced a rapid development in the past few decades. Existing oxide electrolytes are divided into two groups, i.e., crystalline group including NASICON , perovskite, garnet, and some newly developing structures, and amorphous/glass group including Li 2 O–MO x (M = Si, B, P, etc.) and Li PON ‐related materials. After a historical perspective on the general development of oxide electrolytes, we try to give a comprehensive review on the oxide electrolytes with high–lithium‐ion conductivity, with special emphasis on the aspect of materials selection and design for applications as solid electrolytes in lithium batteries. Some successful examples and meaningful attempts on the incorporation of oxide electrolytes in lithium batteries are also presented. In the conclusion part, an outlook for the future direction of oxide electrolytes development is given.