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Elucidating the Role of the Aluminous Source on Limestone Reactivity in Cementitious Materials
Author(s) -
PuertaFalla Guillermo,
Balonis Magdalena,
Le Saout Gwenn,
Falzone Gabriel,
Zhang Carolyn,
Neithalath Narayanan,
Sant Gaurav
Publication year - 2015
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.13806
Subject(s) - metakaolin , cementitious , cement , pozzolan , portland cement , mineralogy , carbonate , pozzolanic reaction , thermogravimetric analysis , materials science , calcium carbonate , chemical engineering , metallurgy , chemistry , composite material , organic chemistry , engineering
When limestone (CaCO 3 ) is present in ordinary portland cement ( OPC ), carbonate‐ AF m phases (i.e., hemi‐ and/or mono‐carboaluminate) are stabilized at the expense of the sulfate‐ AF m, which is more commonly found in cement systems. In OPC , the quantity of AF m hydrates formed is often limited by the availability of aluminum. Therefore, as a means of enhancing AF m phase formation, this study elucidates the role of aluminous sources including: calcium aluminate cements, metakaolin, and a hydratable alumina to determine if their addition would enhance limestone reactions and carbonate‐ AF m formation in cement systems. The results of a detailed study including: X‐ray diffraction, strength measurements, thermogravimetric analysis, and thermodynamic calculations are used to quantify solid phase constitutions, and the extent of limestone reacted. The results suggest that, the amount of limestone reacted and the specific carbonate‐ AF m formed is sensitive to both, the nature of the aluminous source and limestone content. Pozzolanic reactions which occur when metakaolin is used as an aluminous source are noted to be especially beneficial in offsetting the effects of OPC replacement. It is noted that although the different aluminous materials react with different quantities of Ca CO 3 during hydration, enhanced carbonate‐ AF m formation alone is insufficient to ensure strength equivalence, when OPC is replaced by limestone.