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An Upconversion Niobium Pentoxide Bulk Glass Codoped with Er 3+ /Yb 3+ Fabricated by Aerodynamic Levitation Method
Author(s) -
Li Jiaying,
Li Jianqiang,
Li Bo,
Yu Jianding,
Qi Longhao
Publication year - 2015
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.13551
Subject(s) - photon upconversion , materials science , analytical chemistry (journal) , raman spectroscopy , luminescence , differential scanning calorimetry , thermal stability , photoluminescence , niobium oxide , niobium , optoelectronics , optics , chemistry , metallurgy , physics , organic chemistry , chromatography , thermodynamics
(82− x )NbO 2.5 –17.4LaO 1.5 – x ZrO 2 ( NLZ ) ( x = 7.5, 10, 12.5, 15, 17.5, and 20) bulk glasses codoped with Er 3+ /Yb 3+ were successfully fabricated by aerodynamic levitation method for the first time. The structure, thermal stability, and luminescent properties of the samples were investigated systemically by XRD , differential scanning calorimetry, and upconversion spectra. Under 980 nm laser excitation, all samples exhibited green and red upconversion emissions centered at 531, 546, and 674 nm. Results showed that the sample with 15 mol% ZrO 2 obtained the most efficient upconversion luminescence and good thermal stability with the glass‐transition temperature as high as 743 °C. The effect of the addition of ZrO 2 on the structure behavior and the phonon density in the glass was investigated by Raman spectra, which are the key factors for the upconversion luminescence intensity.