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Dependence of Semiconductor to Metal Transition of VO 2 (011)/NiO{100}/MgO{100}/TiN{100}/Si{100} Heterostructures on Thin Film Epitaxy and Nature of Strain
Author(s) -
Bayati Reza,
Molaei Roya,
Wu Fan,
Narayan Jagdish,
Yarmolenko Sergey
Publication year - 2015
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.13454
Subject(s) - materials science , tetragonal crystal system , epitaxy , monoclinic crystal system , non blocking i/o , thin film , heterojunction , crystallography , tin , condensed matter physics , crystal structure , nanotechnology , metallurgy , chemistry , optoelectronics , biochemistry , physics , layer (electronics) , catalysis
We have studied semiconductor to metal transition ( SMT ) characteristics of VO 2 (011) thin films integrated epitaxially with Si(100) through NiO{001}/MgO{001}/TiN{001} buffer layers and correlated with the details of epitaxy and nature of residual stresses and strains across the VO 2 /NiO interface. Thin film epitaxy at both room and elevated temperatures is studied in detail by electron microscopy and in situ high‐temperature X‐ray diffraction techniques. The epitaxial relationship across the interface between monoclinic VO 2 and NiO is determined to be (011) VO 2 ||{100} NiO and [0 1 ¯ 1] VO 2 ||[001] NiO at room temperature. The epitaxial alignment at the temperature of growth where tetragonal VO 2 is stable is determined as: (110) VO 2 ||{100} NiO and [001] VO 2 ||[100] NiO . A cube‐on‐cube crystallographic alignment is established across the NiO{100}/MgO{100}/TiN{100}/Si{100} interfaces. The misfit strains across the VO 2 /NiO interface at the growth temperature are calculated and the mechanism of strain relaxation is discussed. The out‐of‐plane orientation is found to be relaxed in both monoclinic and tetragonal states of VO 2 . It is shown that a compressive strain of 31.65% along the [001] direction of tetragonal VO 2 is fully relaxed via matching of multiple domains. However, a small tensile misfit strain of about 5% along [1 1 ¯ 0] direction cannot relax and remains in the lattice. This tensile residual strain leads to a compressive strain along [001] axis which, in turn, results in an SMT temperature slightly lower than that of freestanding strain‐free VO 2 . SMT characteristics of VO 2 (011) epilayers are assessed where an amplitude of near five orders of magnitude, and a hysteresis of less than 3.6 ° C are obtained. This study introduces VO 2 /NiO thin film heterostructure integrated with silicon as a promising candidate for multifunctional devices with novel characteristics where a combination of sensing, manipulation, and response functions is needed.