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Spinel Mg(Al, Ga) 2 O 4 Solid Solution as High‐Performance Microwave Dielectric Ceramics
Author(s) -
Wu Songping,
Xue Juanjuan,
Fan Yingxian
Publication year - 2014
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.13157
Subject(s) - spinel , solid solution , materials science , ceramic , dielectric , microstructure , raman spectroscopy , analytical chemistry (journal) , sintering , microwave , relative density , grain size , mineralogy , metallurgy , chemistry , optoelectronics , optics , physics , chromatography , quantum mechanics
Spinel Mg ( Al 1− x Ga x ) 2 O 4 ( x = 0–1) solid solutions were synthesized via solid‐state method. Replacement of Al 3+ by Ga 3+ in MgAl 2 O 4 gave rise to the expansion of the lattice, as well as blueshifts of FT ‐ IR and Raman peaks. The homogeneous solid solutions, high relative densities, large grain sizes, and compact microstructures resulted in excellent microwave dielectric properties for spinel Mg ( Al 1− x Ga x ) 2 O 4 ( x = 0.6) ceramics sintered at 1485°C: that is, ε r = 8.87, Q × f = 107 000 GHz (at 14.8 GHz), and τ f = −16 ppm/°C. Spinel‐structured Mg ( Al 1− x Ga x ) 2 O 4 ( x = 0–1) solid solutions possessed low sintering temperatures, wide temperature regions (~100°C), and small negative τ f values. These outstanding performance make Mg ( Al , Ga ) 2 O 4 a promising candidate material for millimeter‐wave devices.