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Phase Separation and Spatial Morphology in Sodium Silicate Glasses by AFM, Light Scattering and NMR
Author(s) -
Hodroj Abbas,
Simon Patrick,
Florian Pierre,
Chopinet MarieHélène,
Vaills Yann
Publication year - 2013
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.12459
Subject(s) - spinodal decomposition , nucleation , materials science , phase (matter) , spinodal , light scattering , silicate , raman scattering , raman spectroscopy , chemical physics , scattering , analytical chemistry (journal) , chemistry , optics , chromatography , physics , organic chemistry
The morphological and structural properties of sodium silicate ( Na 2 O – SiO 2 ) glasses were analyzed using atomic force microscopy ( AFM ) and light scattering following thermal treatments. AFM observations indicated that the glass surface microstructure evolves during the phase separation mechanisms from continuous interpenetrating phases in the spinodal decomposition process to separated droplets embedded in a continuous matrix for the nucleation/growth one. Raman mapping gave evidence of a phase separation through the nucleation/growth process with formation of silica‐rich clusters characterized by higher polymerization degree as separate droplets. The variations in inhomogeneities versus temperature investigated by Brillouin are exponential for spinodal decomposition and linear in the case of nucleation/growth mechanism. Nuclear magnetic resonance spectroscopy was used to investigate the spatial distribution of the various Q n species present in thermally treated glasses and allows determining fractal dimension between two and three.