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Influence of Sintering Aid on the Translucency of Spark Plasma‐Sintered Silicon Nitride Ceramics
Author(s) -
Yang Wenwu,
Hojo Junichi,
Enomoto Naoya,
Tanaka Yumi,
Inada Miki
Publication year - 2013
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/jace.12370
Subject(s) - materials science , spark plasma sintering , microstructure , sintering , silicon nitride , ceramic , fracture toughness , transmittance , composite material , grain boundary , mineralogy , layer (electronics) , optoelectronics , chemistry
Single additives ( Y 2 O 3 , MgO , and Al 2 O 3 ) were used as sintering aid of Si 3 N 4 . The density, crystal phase, microstructure, transmittance, hardness, and fracture toughness of sintered Si 3 N 4 were investigated. Highly densified sintered bodies were obtained in single Y 2 O 3 and MgO systems, but not in single Al 2 O 3 system. The XRD results indicated that sintered bodies were composed of β‐ Si 3 N 4 . The SEM images showed that all the sintered bodies had a fine‐grained microstructure with an average diameter of 0.29–0.37 μm. The thickness of grain boundary was changed with additive content. The transmittance ( T ) and the wavelength (λ) followed the relationship of T∝ exp(−λ −2.3 ) due to the light scattering. The transmittance was mainly influenced by the refractive index of additives and the thickness of grain boundary phase. The hardness and fracture toughness of sintered ceramics were 12.6–15.5 GPa and 6.2–7.2 MPam 1/2 , respectively.