Ceramic Capillary Suspensions: Novel Processing Route for Macroporous Ceramic Materials

We introduce a novel method to produce macroporous ceramics by capillary suspensions. Adding a small amount (~1 vol%) of an immiscible secondary phase to a low concentration (~20 vol%) suspension can increase the yield stress by several orders of magnitude. This drastic change in flow behavior is induced by the creation of a sample‐spanning particle network in the suspension controlled by capillary forces. This strong network may persist even if the primary bulk phase is removed. Accordingly, capillary suspensions can be used as a precursor for manufacturing porous materials. Here, we focus on the specific features of this universal, low‐cost processing route for porous ceramics. An Al 2 O 3 model system is used to demonstrate how to adjust porosity and pore size. With this system, we were able to achieve open porosities higher than 60% with an average pore size below 10 μm.