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Noble gas study of the Saratov L4 chondrite
Author(s) -
MATSUDA Junichi,
TSUKAMOTO Hidetomo,
MIYAKAWA Chie,
AMARI Sachiko
Publication year - 2010
Publication title -
meteoritics and planetary science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.09
H-Index - 100
eISSN - 1945-5100
pISSN - 1086-9379
DOI - 10.1111/j.1945-5100.2010.01026.x
Subject(s) - noble gas , meteorite , chondrite , chemistry , xenon , isotope , analytical chemistry (journal) , residue (chemistry) , krypton , neon , radiochemistry , argon , astrobiology , nuclear physics , chromatography , biochemistry , physics , organic chemistry
– We have determined the elemental abundances and the isotopic compositions of noble gases in a bulk sample and an HF/HCl residue of the Saratov (L4) chondrite using stepwise heating. The Ar, Kr, and Xe concentrations in the HF/HCl residue are two orders of magnitude higher than those in the bulk sample, while He and Ne concentrations from both are comparable. The residue contains only a portion of the trapped heavy noble gases in Saratov; 40 ± 9% for 36 Ar, 58 ± 12% for 84 Kr, and 48 ± 10% for 132 Xe, respectively. The heavy noble gas elemental pattern in the dissolved fraction is similar to that in the residue but has high release temperatures. Xenon isotopic ratios of the HF/HCl residue indicate that there is no Xe‐HL in Saratov, but Ne isotopic ratios in the HF/HCl residue lie on a straight line connecting the cosmogenic component and a composition between Ne‐Q and Ne‐HL. This implies that the Ne isotopic composition of Q has been changed by incorporating Ne‐HL (Huss et al. 1996) or by being mass fractionated during the thermal metamorphism. However, it is most likely that the Ne‐Q in Saratov is intrinsically different from this component in other meteorites. The evidence of this is a lack of correlation between the isotopic ratio of Ne‐Q and petrologic types of meteorites (Busemann et al. 2000). A neutron capture effect was observed in the Kr isotopes, and this process also affected the 128 Xe/ 132 Xe ratio. The 3 He and 21 Ne exposure ages for the bulk sample are 33 and 35 Ma, respectively.