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Rapid contamination during storage of carbonaceous chondrites prepared for micro FTIR measurements
Author(s) -
KEBUKAWA Yoko,
NAKASHIMA Satoru,
OTSUKA Takahiro,
NAKAMURAMESSENGER Keiko,
ZOLENSKY Michael E.
Publication year - 2009
Publication title -
meteoritics and planetary science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.09
H-Index - 100
eISSN - 1945-5100
pISSN - 1086-9379
DOI - 10.1111/j.1945-5100.2009.tb00750.x
Subject(s) - chondrite , fourier transform infrared spectroscopy , carbonaceous chondrite , contamination , materials science , chemistry , chemical engineering , astrobiology , meteorite , ecology , physics , engineering , biology
— Organic contamination (˜2965 and ˜1260 cm −1 peaks) was found on Tagish Lake (C2) and Murchison (CM2) carbonaceous chondrites containing abundant hydrous minerals by Fourier transform infrared (FTIR) microspectroscopy on the samples pressed on Al plates. On the other hand, anhydrous chondrite (Moss, CO3) was not contaminated. This contamination occurred within one day of storage, when the samples pressed on Al were stored within containers including silicone rubber mats. Volatile molecules having similar peaks to the contaminants were detected by long‐path gas cell FTIR measurements for the silicone rubber mat. Rapid adsorption of the volatile contaminants also occurred when silica gel and hydrous minerals such as serpentine were stored in containers including silicone rubber, silicone grease, or adhesive tape. However, they did not show any contamination when stored in glass and polystyrene containers without these compounds. Therefore, precious astronomical samples such as meteorites, interplanetary dust particles (IDPs), and mission‐returned samples from comets, asteroids, and Mars, should be measured by micro FTIR within one day of storage in glass containers without silicone rubber, silicone grease, or adhesive tape.