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Weathering of meteorites from Oman: Correlation of chemical and mineralogical weathering proxies with 14 C terrestrial ages and the influence of soil chemistry
Author(s) -
AlKATHIRI A.,
HOFMANN B. A.,
JULL A. J. T.,
GNOS E.
Publication year - 2005
Publication title -
meteoritics and planetary science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.09
H-Index - 100
eISSN - 1945-5100
pISSN - 1086-9379
DOI - 10.1111/j.1945-5100.2005.tb00185.x
Subject(s) - weathering , chondrite , troilite , meteorite , geology , regolith , mineralogy , geochemistry , chemical composition , chemistry , astrobiology , physics , organic chemistry
Abstract— Fifty‐four fragments of ordinary chondrites from 50 finds representing all searched areas in central Oman and all weathering stages were selected to compare the physical, chemical, and mineralogical effect of terrestrial weathering with 14 C terrestrial ages. 14 C ages range from 2.0 to >49 kyr with a median value of 17.9 kyr. The peak of the age range, which is between 10–20 kyr, falls in an arid climate period. A comparison of the chemical composition of Omani chondrites with literature data for unweathered H and L chondrites demonstrates a strong enrichment in Sr and Ba, and depletion in S during weathering. Water contents in H chondrites increase with terrestrial age, whereas L chondrites show a rapid initial increase followed by nearly constant water content. Correlating Sr, Ba, and H 2 O with age indicates two absorption trends: i) an initial alteration within the first 20 kyr dominated by H 2 O uptake, mainly reflecting Fe‐Ni metal alteration, and ii) a second Ba‐and Sr‐dominated stage correlated with slower and less systematic weathering of troilite that starts after H 2 O reaches −2 wt%. Sulfur released from troilite partly combines with Ba and Sr to form sulfate minerals. Other parameters correlated with 14 C age are degree of weathering, color of powdered meteorites, and the Ni/Fe ratio. Chemical analyses of 145 soils show a high degree of homogeneity over the entire interior Oman Desert, indicating large‐scale mixing by wind. Soil samples collected from beneath meteorite finds typically are enriched in Ni and Co, confirming mobilization from the meteorites. High Cr and Ni concentrations in reference soil samples, which decrease from NE to SW, are due to detrital material from ultramafic rocks of the Oman Mountains.