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Thoroughly anomalous chromium in Orgueil
Author(s) -
PODOSEK F. A.,
OTT U.,
BRAN J. C.,
NEAL C. R.,
BERNATOWICZ T. J.,
SWAN P.,
MAHAN S. E.
Publication year - 1997
Publication title -
meteoritics and planetary science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.09
H-Index - 100
eISSN - 1945-5100
pISSN - 1086-9379
DOI - 10.1111/j.1945-5100.1997.tb01547.x
Subject(s) - murchison meteorite , hydrochloric acid , chemistry , dissolution , magnetite , presolar grains , mineral , meteorite , scanning electron microscope , chromium , analytical chemistry (journal) , mineralogy , geology , chondrite , inorganic chemistry , astrobiology , materials science , environmental chemistry , physics , paleontology , organic chemistry , composite material
— Stepwise dissolution of bulk Orgueil reveals that all of the Cr in the whole rock is isotopically anomalous, with an anomaly pattern that is thus far unique. Most of the Cr (along with other major and minor cations) is dissolved by acetic and nitric acids; it is deficient in 54 Cr by ∼5 ɛ. Subsequent treatment with hydrochloric acid dissolves a small fraction of the Cr with positive 54 Cr anomalies, up to ∼210 ɛ. Mass balance indicates that whole rock Cr is isotopically normal within analytical uncertainties. The least extravagant interpretation of these results is that some mineral phase is enriched in a heavy‐Cr nucleosynthetic component, while most of the Cr is a homogenized mixture of diverse nucleosynthetic components that would be normal except for lack of the postulated heavy Cr carrier. The carrier is likely, but not necessarily, presolar interstellar grains. Its identity is unknown and constrained only circumstantially: it must be relatively rich in Cr, it is substantially soluble in hydrochloric acid, and it is not magnetite or spinel/chromite. Scanning electron microscope (SEM) examination of Orgueil reveals candidate Cr‐rich oxides, silicates, sulfides and phosphides, but none of these can be identified yet as the heavy Cr carrier. Whether presolar or not, the carrier is not chemically resistant and likely not thermally refractory, thereby differing from most other phases known to host isotopic anomalies. Its survival (or production) thus establishes constraints on a different regime of nebular history.