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Synthesis of Pb‐Feldspar by Ion Exchange Reaction and Its Implications
Author(s) -
Rui LIU,
Anhuai LU,
Shan QIN
Publication year - 2006
Publication title -
acta geologica sinica ‐ english edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.444
H-Index - 61
eISSN - 1755-6724
pISSN - 1000-9515
DOI - 10.1111/j.1755-6724.2006.tb00227.x
Subject(s) - feldspar , alkali metal , alkali feldspar , ion , crystal structure , alkaline earth metal , diffraction , x ray photoelectron spectroscopy , chemistry , mineralogy , materials science , crystallography , physics , metallurgy , organic chemistry , quartz , optics , nuclear magnetic resonance
  Feldspar and Pb(NO 3 ) 2 were mixed and reacted at T =380°C to synthesize Pb‐feldspar. In the XRD (X‐ray diffraction) pattern of the product, the d values (crystal lattice spacing) of the five peaks are 0.654, 0.342, 0.332, 0.327 and 0.257 nm. The XPS analysis results show that the binding energy of Pb 4f 7/2 in the feldspar was between 137.81–138.03 eV. Pb 2+ can replace alkali and alkali earth cations in the feldspar structure through ion exchange reaction to form Pb‐feldspar.

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