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MOBILITY AND AQUATIC TOXICITY OF COPPER IN AN URBAN WATERSHED 1
Author(s) -
Boulanger Bryan,
Nikolaidis Nikolaos P.
Publication year - 2003
Publication title -
jawra journal of the american water resources association
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.957
H-Index - 105
eISSN - 1752-1688
pISSN - 1093-474X
DOI - 10.1111/j.1752-1688.2003.tb04387.x
Subject(s) - surface runoff , environmental science , impervious surface , water quality , urban stream , watershed , hydrology (agriculture) , first flush , copper , stormwater , urban runoff , environmental chemistry , streams , daphnia pulex , environmental engineering , cladocera , ecology , chemistry , geology , computer network , geotechnical engineering , organic chemistry , machine learning , computer science , biology , crustacean
Abundant use of copper based products has resulted in increased violation of copper water quality criteria in runoff from urban storm water systems. The objectives of this work were to understand the mobility and toxicity of copper in an urban watershed and to apportion the amount of copper entering the freshwater receiving stream from different urban land covers using a mass balance approach. Sixteen rainfall events collected from the University of Connecticut study watershed between August 1998 and September 2000 were analyzed to assess copper flux in an urban storm water system. Mean flow weighted dissolved copper concentrations observed in the study for copper based architectural material runoff, pervious area runoff, impervious area runoff, and in the receiving stream were 1210 ± 840, 9 ± 3, 8 ± 2, and 14 ± 7 μg/L, respectively. Mean dissolved copper concentrations in the receiving stream exceeded Connecticut's water quality criteria. Despite exceeding the dissolved concentration based criteria, cupric ion concentrations at the system outlet remained below 0.05 μg/L for all storms analyzed, and no acute toxicity (using Daphnia pulex as the test organism) was measured in samples collected from the stream.