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δ 98/95 Mo values and Molybdenum Concentration Data for NIST SRM 610, 612 and 3134: Towards a Common Protocol for Reporting Mo Data
Author(s) -
Greber Nicolas D.,
Siebert Christopher,
Nägler Thomas F.,
Pettke Thomas
Publication year - 2012
Publication title -
geostandards and geoanalytical research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.037
H-Index - 73
eISSN - 1751-908X
pISSN - 1639-4488
DOI - 10.1111/j.1751-908x.2012.00160.x
Subject(s) - nist , molybdenum , analytical chemistry (journal) , homogeneous , chemistry , materials science , chromatography , computer science , inorganic chemistry , thermodynamics , physics , natural language processing
Molybdenum concentration and δ 98/95 Mo values for NIST SRM 610 and 612 (solid glass), NIST SRM 3134 (lot 891307; liquid) and IAPSO seawater reference material are presented based on comparative measurements by MC‐ICP‐MS performed in laboratories at the Universities of Bern and Oxford. NIST SRM 3134 and NIST SRM 610 and 612 were found to have identical and homogeneous 98 Mo/ 95 Mo ratios at a test portion mass of 0.02 g. We suggest, therefore, that NIST SRM 3134 should be used as reference for the δ–Mo notation and to employ NIST SRM 610 or 612 as solid silicate secondary measurement standards, in the absence of an isotopically homogeneous solid geological reference material for Mo. The δ 98/95 Mo JMC Bern composition (Johnson Matthey ICP standard solution, lot 602332B as reference) of NIST SRM 3134 was 0.25 ± 0.09‰ (2 s ). Based on five new values, we determined more precisely the mean open ocean δ 98/95 Mo SRM 3134 value of 2.09 ± 0.07‰, which equals the value of δ 98/95 Mo JMC Bern of 2.34 ± 0.07‰. We also refined the Mo concentration data for NIST SRM 610 to 412 ± 9 μg g −1 (2 s ) and NIST SRM 612 to 6.4 ± 0.7 μg g −1 by isotope dilution. We propose these concentration data as new working values, which allow for more accurate in situ Mo determination using laser ablation ICP‐MS or SIMS.