Premium
Generation of Chemisorbed Benzyl Radicals on Silica Nanoparticles
Author(s) -
Arce Valeria B.,
Rosso Janina A.,
Oliveira Fernando J. V. E.,
Airoldi Claudio,
Soria Delia B.,
Gonzalez Mónica C.,
Allegretti Patricia E.,
Mártire Daniel O.
Publication year - 2010
Publication title -
photochemistry and photobiology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.818
H-Index - 131
eISSN - 1751-1097
pISSN - 0031-8655
DOI - 10.1111/j.1751-1097.2010.00810.x
Subject(s) - benzophenone , flash photolysis , chemistry , silanol , photochemistry , phosphorescence , radical , fumed silica , acetonitrile , spectroscopy , nanoparticle , fourier transform infrared spectroscopy , benzyl alcohol , adsorption , analytical chemistry (journal) , materials science , organic chemistry , chemical engineering , fluorescence , reaction rate constant , catalysis , nanotechnology , physics , quantum mechanics , kinetics , engineering
Functionalized silica nanoparticles (NP) were obtained by esterification of the silanol groups of fumed silica nanoparticles with benzyl alcohol. These particles were characterized by Fourier transform infrared spectroscopy, 13 C and 29 Si NMR spectroscopy, thermogravimetry, total organic carbon, Brunauer–Emmett–Teller analysis, UV‐visible spectroscopy, and transmission electron microscopy. NP suspensions in water/acetonitrile mixtures were used as quenchers of benzophenone (BP) phosphorescence in time‐resolved experiments at the excitation wavelength of 266 nm. The phosphorescence signals obtained in the presence of the nanoparticles were fitted to biexponential decays. Both decays were accelerated in the presence of increasing amounts of NP. A model, including the reversible adsorption of BP on the NP, which was supported by computer simulations accounts for the observed results. Laser flash‐photolysis experiments with excitation at 266 nm of NP suspensions in water/acetonitrile in the presence of BP generated benzyl radicals that were attached to the silica surface. These radicals were detected at their absorption maxima (320 nm) by transient optical techniques.